Legal provisions for optional referendums at national level

Greenland
Answer
Yes
Source
The Constitutional Act of Denmark (1953)
42. (8) Rules for referenda, including the extent to which referenda shall be held in the Faroe Islands and in Greenland, shall be laid down by statute.
See also:
Comment
Constitution of Denmark provides for the possibility of referendums in Greenland. However, no statue has been found to regulate this matter.